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529-0440-00L 6 Credits BSC , MSC D-CHAB , D-MAVT , D-PHYS , D-ITET
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Physical Electrochemistry and Electrocatalysis

Lecturers & Examiners: Prof. Dr. Thomas Schmidt
VVZ CR n/a

Last Updated: 2026-02-05 16:22:34

Abstract

Fundamentals of electrochemistry, electrochemical electron transfer, electrochemical processes, electrochemical kinetics, electrocatalysis, surface electrochemistry, electrochemical energy conversion processes and introduction into the technologies (e.g., fuel cell, electrolysis), electrochemical methods (e.g., voltammetry, impedance spectroscopy), mass transport.

Objective

Providing an overview and in-depth understanding of Fundamentals of electrochemistry, electrochemical electron transfer, electrochemical processes, electrochemical kinetics, electrocatalysis, surface electrochemistry, electrochemical energy conversion processes (fuel cell, electrolysis), electrochemical methods and mass transport during electrochemical reactions. The students will learn about the importance of electrochemical kinetics and its relation to industrial electrochemical processes and in the energy seactor.

Content

Review of electrochemical thermodynamics, description electrochemical kinetics, Butler-Volmer equation, Tafel kinetics, simple electrochemical reactions, electron transfer, Marcus Theory, fundamentals of electrocatalysis, elementary reaction processes, rate-determining steps in electrochemical reactions, practical examples and applications specifically for electrochemical energy conversion processes, introduction to electrochemical methods, mass transport in electrochemical systems. Introduction to fuel cells and electrolysis

Resources

Lecture Notes

Will be handed out during the Semester

Literature

Physical Electrochemistry, E. Gileadi, Wiley VCH Electrochemical Methods, A. Bard/L. Faulkner, Wiley-VCH Modern Electrochemistry 2A - Fundamentals of Electrodics, J. Bockris, A. Reddy, M. Gamboa-Aldeco, Kluwer Academic/Plenum Publishers

General Information

Language
English
Levels
BSC , MSC
Frequency
Yearly recurring

Examination

Type
session examination
Mode
oral 30 minutes

Course Components

Type Title Time & Place Hours
lecture with exercise Physical Electrochemistry and Electrocatalysis
  • Tue 08:00-10:30 (HIL D 10.2)
3 h weekly

Offered In

    • Electives (Students are free to choose from a range of D-CHAB chemistry courses appropriate to their level of study (please note admission requirements). In case of doubt, contact the student administration.)
        • Electives (The Bachelor's programme in Interdisciplinary Sciences allows students to choose from any subject taught at a Bachelor's level at ETH Zurich. In consultation with the Director of Studies of Interdisciplinary Sciences, every student must establish his/her own individual study programme at the beginning of the 2nd year. See the Programme Regulations 2018 for further details.)
    • Electives (These courses are particularly recommended, other ETH-courses from the field of Energy Science and Technology at large may be chosen in accordance with your tutor.)
      • General Electives (Students may choose General Electives from the entire course programme of ETH Zurich - with the following restrictions: courses that belong to the first or second year of a Bachelor curriculum at ETH Zurich as well as courses from GESS "Science in Perspective" are not eligible here. The following courses are explicitly recommended to physics students by their lecturers. (Courses in this list may be assigned to the category "General Electives" directly in myStudies. For the category assignment of other eligible courses keep the choice "no category" and take contact with the Study Administration ( ) after having received the credits.))